Rapid, accurate and inexpensive monitoring of water quality parameters is indispensable for continued water safety, especially in resource-limited areas. Most conventional sensing systems either can only monitor one parameter at a time or lack user-friendly on-site monitoring capabilities. A fully integrated electrochemical sensor array is an excellent solution to this barrier. Electrochemical sensing methods involve transduction of water quality parameters where chemical interactions are converted to electrical signals. The challenge remains in designing low-cost, easy-to-use, and highly sensitive sensor array that can continuously monitor major water quality parameters such as pH, free chlorine, temperature along with emerging pharmaceutical contaminants, and heavy metal without the use of expensive laboratory-based techniques and trained personnel. Here, we overcame this challenge through realizing a fully integrated electrochemical sensing system that offers simultaneous monitoring of pH (57.5 mV/pH), free chlorine (186 nA/ppm), and temperature (16.9 mV/°C) and on-demand monitoring of acetaminophen and 17β-estradiol (<10 nM) and heavy metal (<10 ppb), bridging the technological gap between signal transduction, processing, wireless transmission, and smartphone interfacing. This was achieved by merging nanomaterials and carbon nanotube-based sensors fabricated on microscopic glass slides controlled by a custom-designed readout circuit, a potentiostat, and an Android app. The sensing system can be easily modified and programmed to integrate other sensors, a capability that can be exploited to monitor a range of water quality parameters. We demonstrate the integrated system for monitoring tap, swimming pool, and lake water. This system opens the possibility for a wide range of low-cost and ubiquitous environmental monitoring applications.

Heavy metal pollution is a severe environmental problem affecting many water resources. The non-biodegradable nature of the heavy metals such as lead (Pb) causes severe human health issues, so their cost-effective, sensitive and rapid detection is needed. In this work, we describe a simple, facile and low cost modifications of multiwalled carbon nanotubes (MWCNT) and \b{eta}-cyclodextrin (\b{eta}CD) through non-covalent/physical (Phys) and a covalent Steglich esterification (SE) approaches. The Phys modification approach resulted Pb detection with a limit-of-detection (LoD) of 0.9 ppb, while the SE approach showed an LoD of 2.3 ppb, both of which are well below the WHO Pb concentration guideline of 10 ppb. The MWCNT-\b{eta}CD (Phys) based electrodes show negligible interference with other common heavy metal ions such as Cd2+ and Zn2+. The MWCNT-\b{eta}CD based electrodes were of low-cost owing to their simple synthesis approaches, exhibited good selectivity and reusability. The proposed MWCNT-\b{eta}CD based electrodes is a promising technology in developing a highly affordable and sensitive electrochemical sensing system of Pb in drinking water.

Abstract Accurate, efficient, inexpensive, and multi-parameter monitoring of water quality parameters is critical for continued water safety from developed urban regions to resource-limited or sparsely populated areas. This study describes an integrated sensing system with solution-processed pH, free chlorine, and temperature sensors on a common glass substrate. The pH and temperature sensors are fabricated by low-cost inkjet printing of palladium/palladium oxide and silver. The potentiometric pH sensor has a high sensitivity of 60.6 mV/pH and a fast response of 15 s. The Wheatstone-bridge-based temperature sensor shows an immediate response of 3.35 mV/°C towards temperature change. The free chlorine sensor is based on an electrochemically modified pencil lead, which exhibits a stable and reproducible sensitivity of 342 nA/ppm for hypochlorous acid. Such a free chlorine sensor is potentiostat-free and calibration-free, so it is easy-to-use. The three sensors are connected to a field-programmable gate array board for data collection, analysis and display, with real-time pH and temperature compensation for free chlorine sensing. The developed sensing system is user-friendly, cost-effective, and can monitor water samples in real-time with an accuracy of >82%. This platform enables water quality monitoring by nonprofessionals in a simple manner.