Brines are commonly found at depth in sedimentary basins. Many of these brines are known to be connate waters that have persisted since the early Paleozoic Era. Yet questions remain about their distribution and mechanisms for retention at depth in the Earth's crust. Here we demonstrate that there is insufficient topography to drive these dense fluids from the bottom of deep sedimentary basins. Our assessment based on driving force ratio indicates that sedimentary basins with driving force ratio > 1 contain connate waters and frequently host large evaporite deposits. These stagnant conditions appear to be relatively stable over geological time and insensitive to factors such as glaciations, erosion, compaction, and hydrocarbon generation.

Groundwater resources are being stressed from the top down and bottom up. Declining water tables and near-surface contamination are driving groundwater users to construct deeper wells in many US aquifer systems. This has been a successful short-term mitigation measure where deep groundwater is fresh and free of contaminants. Nevertheless, vertical salinity profiles are not well-constrained at continental-scales. In many regions, oil and gas activities use pore spaces for energy production and waste disposal. Here we quantify depths that aquifer systems transition from fresh-to-brackish and where oil and gas activities are widespread in sedimentary basins across the United States. Fresh-brackish transitions occur at relatively shallow depths of just a few hundred meters, particularly in eastern US basins. We conclude that fresh groundwater is less abundant in several key US basins than previously thought; therefore drilling deeper wells to access fresh groundwater resources is not feasible extensively across the continent. Our findings illustrate that groundwater stores are being depleted not only by excessive withdrawals, but due to injection, and potentially contamination, from the oil and gas industry in areas of deep fresh and brackish groundwater.